New sensors for healthier indoor air

EU qualification programme brings together international doctoral researchers in chemistry, materials science and sensor technology

Air pollution is considered to be one of the world’s biggest environmental problems, but it is often only associated with outdoor air. Yet people spend an average of 22 hours a day indoors, where furniture, carpets or wall paints can release harmful solvents over time. The scientists in the international doctoral programme "SENNET" aim to detect such pollutants. They want to develop reliable sensors based on special, porous materials. Two of the twelve sub-projects are based at Kiel University, where inorganic chemistry and materials science work closely together on that. The main aim of the programme is to provide highly qualified training for doctoral researchers. It is funded by the European union with a total of about 3.2 million euros under the Marie Skłodowska-Curie Actions, about half a million euros will go to Kiel University. Eight universities are involved as well as research institutions and companies as partners. The programme has now officially started with a joint kick-off meeting on 11 and 12 May at the Technical University of Dublin in Ireland.
 

Using porous materials as filters

Most of the hazardous substances in indoor air are so-called volatile organic compounds (VOCs). They can cause damage to health, but are difficult to detect. Currently available miniature sensors (e.g. metal oxide semiconductor sensors) typically cannot distinguish a VOC of interest from, for instance, an air freshener. In order to detect pollutants specifically and reliably, the SENNET programme relies on porous materials, such as so-called metal-organic frameworks (MOFs) and zeolites. Their cavities can only hold certain molecules. "In a way, this works according to the lock-and-key principle and can be used like a kind of filter for selective measurements to reliably detect certain substances," says Norbert Stock, Professor of Inorganic Chemistry at CAU and international MOF expert, explaining the scientific approach of the entire programme.

In his sub-project in the CAU's Inorganic Chemistry, Stock wants to produce MOFs on highly sensitive metal oxide structures. To do so, he is working closely with Professor Rainer Adelung and Dr Leonard Siebert from the Functional Nanomaterials group. The material scientists have investigated and developed these nanostructures for a long time. Having also a long-time-experience in fabricating sensors via 3D printing, they will create complex sensors for detecting multiple pollutants in the second sub-project at Kiel University. "High-performance sensors must above all be sensitive, selective and stable. This means that they must be able to reliably detect even small amounts of the substance over time," says co-subproject leader Dr Leonard Siebert. "With our materials and 3D printing techniques, we hope to improve several factors at once."
 

Qualifying talented young people for different career paths

The EU project brings together expertise from chemistry, physics, materials science and sensor technology and is open to participants from all over the world. The programme includes stays of several months at another partner university as well as in a company and joint conferences of the whole network. In this way, the doctoral researchers will get to know the entire value chain of sensor development and establish international contacts. At the end, they receive a joint degree from their two partner universities. 

"The focus of the programme is to attract talented young researchers from all over the world and to further qualify them for various career options. At the same time, it strengthens international cooperation and networking between basic and applied research as well as industry," says sub-project leader Adelung, emphasising the advantages for doctoral researchers, universities and companies in the region.

Ajay Padunnappattu (right) had specifically been looking for a doctoral position on porous materials like the one with Professor Norbert Stock (left) in Inorganic Chemistry at CAU. He was also attracted by the opportunity to gain experience in international cooperation and industry in the EU programme. Previously, he had completed two master's degrees in chemistry and nanotechnology in India and France.

MORE ABOUT AJAY PADUNNAPPATTU

Two men in a lab
© Julia Siekmann, Uni Kiel

Barnika Chakraborty (front) switched to materials science in Kiel after completing her Master's degree in medicinal chemistry at Pune University in India. She wants to do an interdisciplinary doctorate on new concepts in sensor technology with Professor Rainer Adelung (back) and Dr Leonard Siebert (middle).

 

More about Barnika Chakraborty

Three people in the lab
© Julia Siekmann, Uni Kiel
Group picture
© SENNET

The EU-funded doctoral programme started with a joint kick-off meeting in Dublin. Universities, research institutions and companies from eight countries are involved.

Sensor
© Leonard Siebert

The materials scientists from Kiel produce sensors from highly sensitive metal oxide structures in the 3D printer.

Illustration of a molecular structure
© Dirk Lenzen

Porous materials can only hold certain molecules in their cavities (blue here). As a kind of filter, they enable more selective and reliable sensor measurements than before. The graphic shows the highly porous structure of the material "CAU-10-H", which was developed in Kiel. The name is composed of the location of development, version number and the chemical abbreviation of hydrogen.

 

About the project:

Title: SENNET - Porous Networks for Gas Sensing
Duration: 01.09.2022- 31.08.2026
Period: 48 Months
Funding in total: 3.162.456 Millionen Euro
Funding programme: EU Horizon Europe Research and Innovation Programme, Marie Skłodowska-Curie Actions (MSCA), Agreement No 101072845
Coordination: Katholieke Universiteit Leuven, Belgien

Participants (sorted by EU contribution):

  • Centre National De La Recherche Scientifique (CNRS), France
  • Kiel University / Christian-Albrechts-Universität zu Kiel, Germany
  • Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany
  • Technological University Dublin, Irland
  • Vrije Universiteit Brussel, Belgien
  • Universiteit Gent, Belgien
  • Universitat De Barcelona, Spanien
  • Universitatea Tehnica A Moldovei, Moldau

Project website: https://sennet-project.eu

Contact:

Prof. Dr. Norbert Stock
Inorganic Chemistry
+49 431 880-1675
stock@ac.uni-kiel.de
www.ac.uni-kiel.de/de/stock

 

Prof. Dr. Rainer Adelung
Functional Nanomaterials
+49 431 880-6116
ra@tf.uni-kiel.de
 www.tf.uni-kiel.de/matwis/fnano/de

 

Dr.-Ing. Leonard Siebert
Functional Nanomaterials
+49 431 880-6181
lesi@tf.uni-kiel.de
www.tf.uni-kiel.de/matwis/fnano/de