Exploding and weeping ceramics

Researchers from the University of Minnesota (UMN) and Kiel University (CAU) discover a path to a shape-shifting ceramic material

 

From coffee cups to bathroom tiles, ceramics are brittle.  Subject to the slightest deformation, they shatter. On the other end of the spectrum of materials, some of the most deformable materials known - that also support large stresses while they deform - are shape memory alloys.  The origin of this shape-shifting behavior is a solid-to-solid phase transformation.  Shape memory alloys rely on this tremendous deformability when functioning as medical stents, the backbone of a vibrant medical device industry both in the Twin Cities area Minneapolis-Saint Paul (USA) and in Germany.

In research published open access today on November 17, 2021 in Nature, Eckhard Quandt and Lorenz Kienle from Kiel University (CAU), Andriy Lotnyk from the Leibniz Institute of Surface Engineering (IOM) (all Germany), Richard James from the University of Minnesota (UMN), USA, and their students describe a pathway forward to produce a reversible shape memory ceramic.

The route was anything but straightforward for their graduate students Hanlin Gu(UMN), Jascha Rohmer und Justin Jetter (UMN). They first tried a recipe that has been productive for the discovery of new metallic shape memory materials. That involves a delicate tuning of the distances between atoms by compositional changes, so that the two phases fit together well. They implemented this recipe, but, instead of improving the deformability of the ceramic, they observed that some specimens exploded when they passed through the phase transformation. Others gradually fell apart into a pile of powder, a phenomenon they termed “weeping”.

At yet another composition they observed a reversible transformation, easily transforming back and forth between the phases, much like a shape memory material. The mathematical conditions under which reversible transformation occurs can be applied widely and provide a way forward toward the paradoxical shape-memory ceramic.

With this avenue now open, what can you do with a shape memory ceramic? James says, “It would be a completely new kind of functional material. There is a great need for shape memory actuators that can function in high temperature or in corrosive environments. But what excites us most is the prospect of new ferroelectric ceramics.  In these materials the phase transformation can be used to generate electricity from small temperature differences.”

The team from Germany was responsible for the experimental part and the chemical and structural investigation at the nanoscale. “The collaboration with Richard James’ group was very valuable to explain our experimental discovery: Their theory describes the unexpected behavior of the extremely incompatible ceramics and also shows how to get compatible shape memory ceramics”,.says Eckhard Quandt.

“Our collaboration with Eckhard Quandt’s group has been tremendously productive”, adds James.  “As in all such collaborations, there is sufficient overlap that we communicate well, but each group brings plenty of ideas and techniques that expand our collective ability to discover.

The researchers were supported by the U.S. National Science Foundation, a Vannevar Bush Faculty Fellowship on the `Mathematical Design of Materials’ from the U.S. Department of Defense, a Multidisciplinary University Research Initiatives (MURI) grant from the Office of Naval Research, a Mercator Fellowship from the German Research Foundation, and the Reinhart Koselleck Project from the German National Science Foundation.

Original publication

Exploding and weeping ceramics, Hanlin Gu, Jascha Rohmer, Justin Jetter, Andriy Lotnyk, Lorenz Kienle, Eckhard Quandt, Richard D. James, Nature DOI: 10.1038/s41586-021-03975-5 https://www.nature.com/articles/s41586-021-03975-5

Contact:

Prof. Dr.-Ing. Eckhard Quandt
Kiel University  
Inorganic Functional Materials
eq@tf.uni-kiel.de
+49 431 880-6200
www.tf.uni-kiel.de/matwis/afm/

 

Richard D. James
University of Minnesota
Distinguished McKnight University Professor, Aerospace Engineering and Mechanics
james@umn.edu
+1612-625-0706
https://dept.aem.umn.edu/~james/research/

 

Video material

The videos show how the ceramic material surprisingly explodes (video 1), jumps into the air (video 2) or disintegrates into its individual parts (video 3) during cooling. Video 4, on the other hand, shows a functioning reversible transformation.

 

Two men in front of a bookshelf
© Julia Siekmann, Kiel University

Professor Eckhard Quandt (CAU, left) and Professor Richard D. James, University of Minnesota, are collaborating on new shape memory materials since many years. Here during a research visit to Kiel in 2019 (archive image).

Grafik
© Jascha Rohmer

Upon cooling, ZrO2-based shape memory ceramics undergo phase transformation from a tetragonal to a monoclinic crystal structure. Top (a): Although the composition of the material predicts high compatibility, the ceramic disintegrates into its grains. In the ceramic in the bottom example (b), which satisfies the so-called equidistance condition, the crystal withstands the transformation (the dashed line shows the location of the phase transition).

About KiNSIS:

The nanoworld is governed by different laws than the macroscopic world, by quantum physics. Understanding structures and processes in these dimensions and implementing the findings in an application-oriented manner is the goal of the priority research area KiNSIS (Kiel Nano, Surface and Interface Science) at Kiel University. Intensive interdisciplinary cooperation between physics, chemistry, engineering and life sciences could lead to the development of novel sensors and materials, quantum computers, advanced medical therapies and much more.www.kinsis.uni-kiel.de/en

Press Contact:
Julia Siekmann
Science Communication Officer, Research area Kiel Nano Surface and Interface Sciences