Publications
2011-today
2010-2006
2005-2001
2000-1996
1995-1991
1990-1986
1985-1981
1980-1979
other publications involving
group members
Ph.D. theses
Diploma and B.Sc. theses
Publications
2011
- today:
- K.
Röttger, R. Siewertsen, F. Temps, "Ultrafast Electronic
Deactivation Dynamics of the Rare Nucleobase Hypoxanthine", Chem. Phys.
Lett. 536, 140 - 146 (2012). DOI: 10.1016/j.cplett.2012.03.106.
- J.
Bahrenburg, K.
Röttger, R. Siewertsen, F. Renth, F. Temps, "Sequential
Photoisomerisation Dynamics of the Push-Pull-Azobenzene Disperse Red
1", Photochem. Photobiol. Sci. 11, xxx - yyy (2012), in press. DOI: 10.1039/C2PP05400K.
- H. Nicken, F. Temps, E. Jalviste: "Dispersed Fluorescence Spectra of 1H- and 1D-Indazole", Z. Phys. Chem. 225, 1457 - 1469 (2011). DOI: 10.1524/zpch.2011.0197 (Katharina Kohse-Höinghaus Festschrift).
- R. Siewertsen, F.
Strübe, J. Mattay, F. Renth, F. Temps:
"Electronic and Steric Effects on the Photo-Induced C - E Ring-Opening
of Structurally Modified Furylfulgides", Phys. Chem. Chem. Phys. 13, 15699 - 15707 (2011). DOI: 10.1039/C1CP21320B.
- N. K. Schwalb, R. Siewertsen, F. Renth, F. Temps:
"Pump-Probe Spectroscopy of Ultrafast Vibronic Dynamics in Organic
Chromophores", in: Conical Intersections. Theory, Computation and Experiment. Advanced Series in Physical Chemistry, Vol. 17.
W. Domcke, D. R. Yarkony, H. Köppel (Eds.), pp. 669 - 714, World Scientific,
Singapore, 2011.
- M. Yang, L. Szyc, K. Röttger, H. Fidder, E. T. J.
Nibbering, T. Elsaesser, F. Temps: "Dynamics and Couplings of N-H
Stretching Excitations of Guanosine-Cytidine Base Pairs in Solution",
J. Phys. Chem. B 115, 5484 - 5492 (2011). DOI: 10.1021/jp110561d.
- F. Strübe, R. Siewertsen, F. D. Sönnichsen, F. Renth,
F. Temps, J. Mattay: "Photochromism of Rotation-Hindered Furylfulgides
Influenced by Steric Modifications", Eur. J. Org. Chem. 1947 - 1955 (2011). DOI: 10.1002/ejoc.201001649.
- R. Siewertsen, F. Strübe, J. Mattay, F. Renth, F. Temps:
"Tuning of Switching Properties and Excited-State Dynamics of Fulgides
by Structural Modifications", Phys. Chem. Chem. Phys. 13, 3800 - 3808 (2011). DOI: 10.1039/C0CP01890B.
- R. Siewertsen, J. B. Schönborn, B. Hartke, F.
Renth, F. Temps: "Superior Z - E and E - Z Photoswitching Dynamics of
Dihydrodibenzodiazocine, a Bridged Azobenzene, by S1(nπ*)
Excitation at λ = 387 and 490 nm", Phys. Chem. Chem. Phys. 13, 1054 - 1063 (2011). DOI: 10.1039/C0CP01148G
- M. C. Stuhldreier, C. Schüler, J. Kleber, F.
Temps:
"Femtosecond Fluorescence Measurements of the Adenine Dinucleotide:
Direct Observation of the Excimer State", in: Ultrafast Phenomena XVII,
pp. 553 - 555, M. Chergui, D. M. Jonas, E. Riedle, R. W. Schoenlein, A. J. Taylor (Eds.),
Oxford University Press, Oxford, 2011.
Publications
2006
- 2010:
- G. Friedrichs, J. Bock, F. Temps, P. Fietzek, A.
Körtzinger, D. W. R. Wallace: "Towards
Continuous
Monitoring of Seawater 13CO2/12CO2
Isotope Ratio and pCO2: Performance of Cavity
Ringdown Spectroscopy and Gas Matrix Effects",
Limnol. Oceanogr. Methods 8, 539 - 551 (2010). DOI: 10.4319/lom.2010.8.539
- N. K. Schwalb, T. Michalak, F. Temps: "Ultrashort
Fluorescence Lifetimes of Hydrogen-Bonded Base Pairs of Guanosine and
Cytidine in Solution", J.
Phys. Chem. B 113,
16365 - 16376 (2009). DOI: 10.1021/jp904883n
- R. Siewertsen, H. Neumann, B.
Buchheim-Stehn, R.
Herges, C. Näther, F. Renth, F. Temps: "Highly Efficient
Reversible Z - E
Photoisomerization of a Bridged
Azobenzene with Visible Light through Resolved S1(nπ*)
Absorption Bands", J. Am. Chem. Soc. 131,
15594 - 15595 (2009). DOI: 10.1021/ja906547d.
- N. K. Schwalb, F. Temps: "On the Structure and
Photostability of
Cytosine Self-Assemblies with Extended
Hydrogen-Bonding Networks", J.
Photochem. Photobiol. A: Chemistry 208,
164 - 170 (2009). DOI: 10.1016/j.jphotochem.2009.09.011
- N. K. Schwalb, F. Temps: "A Modified Four-State Model for
the 'Dual Fluorescence' of N6,N6-Dimethyladenine
derived from Femtosecond Fluorescence Spectroscopy", J. Phys. Chem. A 113, 13113
– 13123 (2009). DOI:
10.1021/jp9021773
- R. Siewertsen, F. Renth, F. Temps, F. Sönnichsen:
"Parallel Ultrafast E-C Ring Closure and E-Z Isomerisation in a
Photochromic Furylfulgide Studied by Femtosecond Time-Resolved
Spectroscopy", Phys. Chem. Chem. Phys. 11,
5952 - 5961 (2009). DOI:
10.1039/b821344e
- G. Friedrichs, E. Goos, J. Gripp, H. Nicken, J.-B.
Schönborn, H. Vogel, F. Temps: "The Products of the Reactions
of
o-Benzyne with Ethene, Propene, and Acetylene: A Combined Mass
Spectrometric and Quantum Chemical Study", Z. Phys. Chem. 223, 387 - 407
(2009). DOI: 10.1524/zpch.2009.6042
- N. K. Schwalb, F. Temps: "Femtosecond Fluorescence
Spectroscopy
of N6,N6-Dimethyladenine:
New Explanation of the
'Dual Fluorescence' Dynamics from Decay and Rise Time Measurements at
Threshold", in Ultrafast Phenomena XVI,
pp. 352 - 354, P. Corkum, S. De Silvestri, K. A. Nelson, E.
Riedle, R. W. Schoenlein (Eds.), Springer Series in
Chemical Physics, Vol. 92, 2009.
- G. Friedrichs, M. Fikri, Y. Gua, F. Temps: "Time-Resolved
Cavity Ringdown Measurements and Kinetic Modeling of the Pressure
Dependence of the Recombination Reactions of SiH2
with the
Alkenes C2H4, C3H6,
and t-C4H8,"
J.
Phys. Chem. A 112,
5636 - 5646
(2008). DOI: 10.1021/jp8012128
- H. Studzinski, S. Zhang, Y. Wang, F. Temps: "Ultrafast
Non-Radiative Dynamics in Electronically Excited Hexafluorobenzene by
Femtosecond Time-Resolved Mass Spectrometry", J. Chem. Phys. 128, 164314 (2008).
DOI: 10.1063/1.2907859
- C. Rensing, H. Mäder, F. Temps: "Rotational
Spectrum,
Structure and Internal Dynamics of the Pyrrole ∙ Ammonia Complex", J.
Mol. Spectrosc. 251,
224 - 228
(2008). DOI: 10.1016/j.jms.2008.02.024
- E. Jalviste, S. Dziarzhytski, F. Temps: "Electronic Spectra
of
Hydrogen-Bonded Self and Water Complexes of Indazole", Z. Phys. Chem. 222, 695 - 714
(2008). DOI: 10.1524/zpch.2008.5347
- N. K. Schwalb, F. Temps: "Ultrafast Electronic Relaxation
in
Guanosine is Promoted by Hydrogen Bonding with Cytidine", J. Am. Chem.
Soc. 129,
9272 - 9273
(2007). DOI: 10.1021/ja073448+
- N. K. Schwalb, F. Temps: "A Femtosecond Time-Resolved
Investigation of Dual Fluorescence from
N6,N6-Dimethyladenine",
Phys.
Chem. Chem. Phys. 8,
5229 - 5235 (2006).
- F. Renth, M. Foca, A. Petter, F. Temps: "Ultrafast
Transient
Absorption Spectroscopy of the Photo-Induced Z-E Isomerization of a
Photochromic Furylfulgide," Chem.
Phys. Lett. 428,
62 -
67
(2006).
- W. Ludwig, B. Brandt, G. Friedrichs, F. Temps: "Kinetics of
the
Reaction C2H5 + HO2
by Time-Resolved
Mass Spectrometry", J.
Phys. Chem. A 110,
3330 - 3337 (2006). J.
Troe
Festschrift.
- F. Renth, J. Riedel, F. Temps: "Inversion of Velocity Map
Ion
Images using Iterative Regularization and Cross Validation," Rev. Sci. Instrum. 77, 033103/1 - 12
(2006).
Publications
2001
- 2005:
- G. Friedrichs, M. Colberg, M. Fikri, Z. Huang, J. Neumann,
F.
Temps: "Validation of an Extended Simultaneous Kinetics and Ringdown
Model by Measurements of the Reaction NH2 + NO",
J. Phys. Chem. A
109,
4785 - 4795 (2005).
- J. Riedel, S. Dziarzhytski, A. Kucmann, F. Renth, F. Temps:
"Velocity Map Imaging of H Atoms from the Dissociation of HCO (A 2A”)
using Doppler-Free Multi-Photon Ionization"; Chem. Phys. Lett. 414, 473 - 478
(2005).
- T. Pancur, K. Brendel, N. Hansen, H. Mäder, V.
Markov, F.
Temps: "Microwave Spectra of the 35Cl and 37Cl
Isotomopers of
Dichloromethylene: Nuclear Quadrupole, Spin-Rotation and Nuclear
Shielding Constants from the Hyperfine Structures of Rotational Lines,"
J. Mol. Spectrosc.
232, 375
- 379 (2005).
- T. Pancur, F. Renth, F. Temps, B. Harbaum, A.
Krüger, R.
Herges, Chr. Näther: "Femtosecond fluorescence up-conversion
spectroscopy of a rotation-restricted azobenzene after excitation to
the S1 state," Phys.
Chem. Chem.
Phys. 7,
1985 - 1989
(2005).
- T. Pancur, N. K. Schwalb, F. Renth, F. Temps: "Femtosecond
Fluorescence Up-Conversion Spectroscopy of Adenine and Adenosine:
Experimental Evidence for the πσ* State?" Chem. Phys. 313, 199 - 212
(2005).
- F. Temps: "Comments on Photodissociation of Pyrrole:
Evidence for
Mode Specific Dynamics from Conical Intersections," Faraday Discussion 127 -
Non-Adiabatic
Effects in Chemical Dynamics 127,
355 - 360 (2004).
- J. Wei, J. Riedel, A. Kuczmann, F. Renth, F. Temps:
"Photodissociation of Pyrrole: Evidence for Mode Specific Dynamics from
Conical Intersections," Faraday
Discussion 127 - Non-Adiabatic Effects in Chemical Dynamics
127, 267
- 282 (2004).
- J. Wei, A. Tröllsch, C. M. Tesch, F. Temps:
"Rotational
State Dependent Mixings between Resonance States of Vibrationally
Highly Excited DCO ( 2A')," J. Chem.
Phys. 120,
10530 -
10542 (2004).
- Y. Guo, M. Fikri, G. Friedrichs, F. Temps: "An Extended
Simultaneous Kinetics and Ringdown Model: Determination of the Rate
Constant for the Reaction SiH2 + O2,"
Phys.
Chem. Chem. Phys. 5,
4622 - 4630 (2003).
- R. Deters, H. Gg. Wagner, A. Bencsura, K. Imrik, S. Dobe,
T.
Berces, F. Marta, F. Temps, T. Turanyi, I. G. Zsely: "Direct Kinetic
Determination of Rate Parameters for the Reaction CH3 + OH.
Implications for Methane Flame Modeling," Proc. Eur. Combust. Symp.
(2003).
- F. Renth, A. Tröllsch, F. Temps:
"Intramolecular
Vibrational Energy Redistribution, Mode Specificity, and
Non-Exponential Unimolecular Decay of Vibrationally Highly Excited
States of DCO (X 2A')", J. Chem. Phys.
118, 659
- 668 (2003).
- J. Wei, A. Kucmann, J. Riedel, F. Renth, F. Temps:
"Photofragment
Velocity
Map Imaging of H Atom Elimination in the First Excited State of
Pyrrole", Phys. Chem. Chem. Phys. 5, 315 - 320
(2003).
- T. Köcher, C. Kerst, G. Friedrichs, F. Temps: "The
Gas Phase
Oxidation
of Silyl Radicals by Molecular Oxygen: Kinetics and Mechanisms", in: Silicon
Chemistry - From Small Molecules to Extended Systems, eds. P.
Jutzi
and
U. Schubert, Wiley-VCH, pp. 44 - 57 (2003).
- G. Eshchenko, T. Köcher, C. Kerst, F. Temps:
"Formation of
HCNO
and HCN in the 193 nm Photolysis of H2CCO in the
Presence of
NO", Chem. Phys. Lett. 356, 181
- 187 (2002).
- N. Hansen, H. Mäder, F. Temps:
"Rotational Transitions
of the C2H3O Radical
Detected by Pulsed Laser
Photolysis - Molecular Beam - Fourier Transform Microwave
Spectroscopy", J. Mol. Spectrosc. 209,
278 - 279 (2001).
- M. Fikri, St. Meyer, J. Roggenbuck, F. Temps: "An
experimental
and
theoretical study of the product distribution of the reaction CH2
(X 3B1) + NO," Faraday
Discuss. Roy. Soc.119,
223 - 242 (2001).
- N. Hansen, H. Mäder, F. Temps: "The
Rotational
Spectrum
of CCl2 (X 1A1)
Observed by Molecular
Beam
- Fourier Transform Microwave Spectroscopy", Phys. Chem.
Chem.
Phys. 3, 50 - 55 (2001).
- F. Temps, A. Troellsch: "Analysis of highly excited
vibrational
bound
and resonance states of DCO (X 2A)
using an
effective polyad
model Hamiltonian", Z. Phys. Chem. 215,
207 - 232
(2001) (invited
paper; J. Troe Festschrift).
Publications
1996
- 2000:
- N. Hansen, H. Mäder, F. Temps: "Nuclear
Spin-Rotation
Interaction in CF2 (X 1A1)
Observed
by
Fourier-Transform Microwave Spectroscopy", Chem. Phys. Lett.
327,
97 - 103 (2000).
- C. Oehlers, H. Gg. Wagner, H. Ziemer, F. Temps, S.
Dóbé: "An Investigation of the D/H
Addition-Elimination
and H Atom Abstraction Channels in the Reaction of D + H2CO
in the Temperature Range
296 K < T < 780 K", J. Phys. Chem. A 104,
10500 -
10510
(2000) (C. B. Moore Festschrift).
- St. Meyer, F.Temps: "An FTIR Product Study of the Reaction
between HCO and NO2", Int. J. Chem.
Kinet. 32,
136-145
(2000).
- J. Gripp, A. Kuczmann, C. Stöck, F. Temps, A.
Tröllsch:
"The
(B 2A' - X 2A') Laser
Induced Fluorescence
Excitation Spectrum of DCO in a Supersonic Jet Expansion", Phys.
Chem. Chem. Phys. 2, 1653-1657 (2000).
- N. Hansen, F. Temps, H. Mäder, N. W. Larsen:
"Analysis of
Internal Rotations in Ethyl Nitrite using Molecular Beam Fourier
Transform Microwave Spectroscopy", Phys. Chem. Chem. Phys. 1, 3219-3233
(1999).
- E. Jalviste, F. Temps: "Vibronic spectroscopy of jet-cooled
indazole: S1 - S0
spectra and
mode assignments", J. Chem. Phys.111,
3898-3910 (1999).
- J. Nolte, H. Gg. Wagner, T. J. Sears, F. Temps: "The Far
Infrared
Laser Magnetic Resonance Spectrum of CH2F", J.
Mol.
Spectrosc.195, 43-53 (1999).
- U. Eickhoff, F. Temps: "An FTIR Study of the Products of
the
Reaction between HCCO and NO", Phys. Chem. Chem. Phys.
1,
243-251 (1999).
- R. Deters, M. Otting, H. Gg. Wagner, F. Temps, S.
Dóbé: "Rate Constant for the Reaction CH3
+ CH2
(X 3B1)", Ber.
Bunsenges. Phys. Chem. 102,
978-981 (1998).
- H. Ziemer, S. Dóbé, M. Olzmann, B.
Viskolcz, H. Gg.
Wagner, F. Temps: "Kinetics of the Reactions of HCO with H and D
Atoms", Ber. Bunsenges. Phys. Chem. 102,
897-905 (1998).
- N. Hansen, U. Andresen, H. Dreizler, J.-U. Grabow, H.
Mäder,
F. Temps: "Fourier-Transform Microwave Detection of SO (X 3,
v = 0 - 2) Produced by 193 nm Photolysis of SO2
in a
Supersonic Free
Jet Expansion", Chem. Phys. Lett. 289, 311-318
(1998).
- J. Roggenbuck, F. Temps: "An ab Initio Study of the
Reaction
between CH2 (X 3B1)
and NO.
Determination of Selected Reaction Pathways and Calculation of Barrier
Heights", Chem. Phys. Lett. 285, 422-428 (1998).
- R. Deters, M. Otting, H. Gg. Wagner, F. Temps, B.
László, S. Dóbé, T.
Bérces: "A
Direct Investigation of the Reaction
CH3 + OH at T = 298 K: Overall Rate Coefficient
and CH2
Formation", Ber. Bunsenges. Phys. Chem. 102,
58-72
(1998).
- J. Nolte, H. Gg. Wagner, F. Temps, T. J. Sears: "Far
infrared
laser magnetic resonance detection of CF3, CHF2,
and CH2F", Ber. Bunsenges. Phys. Chem.
101,
1421-1428 (1997).
- H.-M. Keller, M. Stumpf, T. Schröder, C.
Stöck, F.
Temps, R. Schinke, H.-J. Werner, C. Bauer, P. Rosmus: "Unimolecular
Dissociation Dynamics of Highly Vibrationally Excited DCO (X 2A'):
II. Calculation of Resonance Energies and Widths and Comparison with
High Resolution Spectroscopic Data", J. Chem. Phys.
106,
5359-5378 (1997).
- C. Stöck, X. Li, H.-M. Keller, R. Schinke, F.
Temps:
"Unimolecular Dissociation Dynamics of Highly Vibrationally Excited DCO
(X 2A'): I. Investigation of Dissociative
Resonance States
by Stimulated Emission Pumping Spectroscopy", J. Chem. Phys.
106,
5333-5358 (1997).
- J. Grußdorf, F. Temps, H. Gg. Wagner: "An FTIR
Study of the
Reaction CH2 + NO", Ber. Bunsenges.
Phys. Chem. 101,
134-138 (1997).
- S. Dóbé, T. Bérces, T.
Turanyi, F. Marta, J.
Grußdorf, F. Temps, H. Gg. Wagner: "Direct Kinetic Studies of
the
Reactions
Br + CH3OH and CH2OH +
HBr: The Heat of Formation
of
CH2OH", J. Phys. Chem. 100,
19864-19873
(1996).
Publications
1991
- 1995:
- S. Dertinger, A. Geers, J. Kappert, F. Temps, J. W.
Wiebrecht:
"Rotation-Vibration State Resolved Unimolecular Dynamics of Highly
Vibrationally Excited CH3O (X 2E):
III. State
Specific Dissociation Rates from Spectroscopic Line Profiles and Time
Resolved Measurements", Faraday Discuss. Roy. Soc. 102,
31-52 (1995), invited paper.
- F. Temps: "Zur Dynamik hoch schwingungsangeregter
Moleküle
in einzelnen Quantenzuständen", Habilitationsschrift,
Max-Planck-Institut für Strömungsforschung, Bericht
11/1995,
ISSN 0436-1199.
- F. Temps: "Intramolecular Dynamics and State Specific
Unimolecular Dissociation of CH3O (X 2E)",
in: Molecular
Dynamics and Spectroscopy by Stimulated Emission Pumping,
Eds. H.
L. Dai und
R. W. Field, World Scientific, Singapore, 1995, pp. 375, invited paper.
- F. Temps: "Fortschritte der Reaktionskinetik", Nachrichten
aus Chemie, Technik und Laboratorium, 195-197 (1995), invited
paper.
- T. J. Sears, F. Temps, H. Gg. Wagner, M. Wolf: "Far
Infrared
Laser Magnetic Resonance Spectroscopy of CH2Cl",
J. Mol.
Spectrosc.168, 136-146 (1994).
- T. Bérces. S. Dóbé, F.
Temps, H. Gg. Wagner,
H. Ziemer: "Formation of Methoxy and Hydroxymethyl Free Radicals in
Selected Elementary Reactions", 25th Symposium (International) on
Combustion, p.
775. The Combustion Institute, Pittsburgh, 1994.
- S. Dóbé, F. Temps, H. Gg. Wagner, H.
Ziemer, T.
Bérces: "Kinetics of the Reaction Between Hydroxymethyl
Radicals
and Hydrogen Atoms", J. Phys. Chem. 98,
9792-9800
(1994).
- A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht:
"Rotation-Vibration State Resolved Unimolecular Dynamics of Highly
Vibrationally Excited CH3O (X 2E):
II.
Intramolecular Vibrational Dynamics of "C-O Stretch" States", J.
Chem. Phys. 101, 3634-3648 (1994).
- A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht:
"Rotation-Vibration State Resolved Unimolecular Dynamics of Highly
Vibrationally Excited CH3O (X 2E):
I. Stimulated
Emission Pumping Spectra", J. Chem. Phys. 101,
3618-3633 (1994).
- J. Nolte, F. Temps, H. Gg. Wagner, M. Wolf, and T. J.
Sears: "Far
Infrared Laser Magnetic Resonance Detection of CHD (X 3A")",
J. Chem. Phys. 100,
8706-8712 (1994).
- S. Dóbé, C. Oehlers, F. Temps, H. Gg.
Wagner, H.
Ziemer: "Observation of an H/D Isotope Exchange Channel in the Reaction
D + H2CO" Ber. Bunsenges. Phys. Chem.
98,
754-757 (1994).
- H. E. Radford, M. A. Moore, T. J. Sears, J.
Grußdorf, J.
Nolte, F. Temps: "Far Infrared Laser Magnetic Resonance of X 2A'
trans-DOCO", J. Mol. Spectrosc. 165,
137-149
(1994).
- J. Grußdorf, J. Nolte, F. Temps, H. Gg. Wagner:
"Primary
Products of the Elementary Reactions of CH2CO
with F, Cl,
and OH in the Gas Phase", Ber. Bunsenges. Phys. Chem.98,
546-553 (1994).
- J. Nolte, J. Grußdorf, F. Temps, H. Gg. Wagner:
"Kinetics
of the Reaction of HOCO with O2 in the Gas
Phase", Z.
Naturforsch.48a, 1234-1238 (1993).
- H. Kraus, C. Oehlers, F. Temps, H. Gg. Wagner "Kinetics of
the
Reactions of CH2 (X 3B1)
with
Selected Polycyclic Aromatic Hydrocarbons at Temperatures between 296 K
< T < 690 K", J. Phys. Chem. 97,
10989-10995
(1993).
- A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht: "Direct
Measurements of State Specific Unimolecular Dissociation Rate Constants
of Highly Excited Single Rotation Vibration Quantum States of CH3O
(X 2E)", J. Chem. Phys. 99,
2271-2274
(1993).
- A. Geers, J. Kappert, C. Stöck, F. Temps, J. W.
Wiebrecht:
"Quantenzustandsaufgelöste Untersuchungen der
Schwingungsdynamik
und unimolekularen Dissoziation hochangeregter Moleküle am
Beispiel CH3O (X 2E) = H
+ H2CO: Neue
Erkenntnisse über unimolekulare chemische
Elementarreaktionen", Nachr.
Akad. Wiss. Göttingen, Math.-Phys. Klasse, 13 - 30
(1993 [No.
2]), invited paper.
- S. Dóbé, M. Otting, F. Temps, H. Gg.
Wagner, H.
Ziemer: "Fast Flow Studies of the Reaction CH2OH
+ HCI = CH3OH
Cl. The Heat of Formation of Hydroxymethyl", Ber. Bunsenges.
Phys.
Chem.97, 877-884 (1993).
- H. Kraus, C. Oehlers, F. Temps, H. Gg. Wagner, M. Wolf:
"Rate
Constants for the Reaction of 3CH2
(X 3B1)
with Selected Alkenes at Temperatures between 296 K < T <
728 K", Ber. Bunsenges. Phys. Chem. 97,
545-553 (1993).
- A. Geers, J. Kappert, F. Temps, T. J. Sears: "Stimulated
Emission
Pumping Spectroscopy of CH3O (X 2E,
v6):
New Observations on the Jahn-Teller Effect", J. Chem. Phys.
98,
4297-4300 (1993).
- U. Bley, F. Temps: "Collision-Induced Intersystem Crossing
of CH2
from a 1A1 to X 3B1:
A
Case Study
of the Mixed- State Model", J. Chem. Phys. 98,
1058-1072 (1993).
- F. Temps, H. Gg. Wagner, M. Wolf: "Some Experiments
concerning
the Reactions of HCCO with C2H2,
O2,
NO, and NO2", Z. Phys. Chem.
176, 27-39
(1992).
- U. Bley, M. Koch, F. Temps, H. Gg. Wagner: "Investigations
of the
Perturbed-State Model for the Collision-Induced Intersystem Crossing
Transfer CH2 (a 1A1)
+ M = CH2
( X 3B1) + M by Selected
Collision Partners",
Max-Planck-Institut für Strömungsforschung, Report 12
(1992),
ISSN 0436-1199.
- U. Bley, M. Koch, F. Temps, H. Gg. Wagner: "Line-Broadening
Measurements of CH2 (X 3B1)
Rotational Transitions by Far Infrared Laser Magnetic Resonance", J.
Mol. Spectrosc.156, 154-163 (1992).
- U. Bley, F. Temps, H. Gg. Wagner, M. Wolf: "Investigations
of the
Reaction between CH2 (X 3B1)
and O2
in the Temperature Range 233 K < T < 433 K", Ber.
Bunsenges.
Phys. Chem. 96, 1043-1048 (1992).
- F. Temps, H. Gg. Wagner, M. Wolf: "Far Infrared Laser
Magnetic
Resonance Detection of CH2Cl", Z.
Naturforsch. 47a,
660-664 (1992).
- C. Oehlers, F. Temps, H. Gg. Wagner, M. Wolf: "Kinetics of
the
Reaction of OH Radicals with CH2CO", Ber.
Bunsenges.
Phys. Chem.96, 171-175 (1992).
- U. Bley, M. Koch, F. Temps, H. Gg. Wagner, M. Wolf:
"Untersuchungen der Reaktion CH2 (X 3B1)
+ O2 Produkte im Temperaturbereich 233 K
< T < 433 K",
Max-Planck-Institut für Strömungsforschung, Report 12
(1991),
ISSN 0436-1199.
- F. Temps, H. Gg. Wagner: "Kinetics of Reactions of
Prototypical
Aromatic Hydrocarbons with O (3P) Atoms and CH2
(X 3B1) Radicals: A
Comparative Study", ACS
Symposium on Combustion Chemistry, National Meeting of the American
Chemical Society, New York, 1991; Fuel Chemistry 36,
1469-1477 (1991).
- A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht:
"Collisional
Relaxation of CH3O (A 2A1,
v3=1,
K=9, N=9, J=8.5) by He", Chem. Phys. Lett. 178,
317-324
(1991).
- U. Bley, P. B. Davies, M. Grantz, T. J. Sears, F. Temps:
"The FIR
LMR Spectrum of FO2: Some Classic Examples of
Anticrossing
Resonances", Chem. Phys. 152,
281-292 (1991), invited
paper.
Publications
1986
- 1990:
- M. Koch, J. W. C. Johns, L. Nemes, F. Temps, H. Gg. Wagner:
"Far
Infrared Lasing in CH2CO: Observed Emissions and
Spectroscopic
Assignments", Max-Planck-Institut für
Strömungsforschung,
Report
13 (1990), ISSN 0436-1199.
- A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht:
"Preparation of
Single Rotation Vibration States of CH3O (X 2E)
above
the H-CH2O Dissociation Threshold by Stimulated
Emission
Pumping", Ber. Bunsenges. Phys. Chem. 94,
1219-1224
(1990).
- A. Goldbach, F. Temps, H. Gg. Wagner: "Kinetics of the
Reactions
of CH2 (X 3B1)
with HCl and HBr", Ber.
Bunsenges. Phys. Chem. 94, 1367-1371
(1990).
- A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht:
"Stimulated
Emission Pumping Spectroscopy of Highly Excited States of CH3O
(X 2E): Zero-Order Vibrational States at 3000 cm-1
<
Ev < 9000 cm-1", J.
Opt. Soc. Am. B. 7,
1935-1943 (1990), invited paper.
- A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht:
"Stimulated
Emission Pumping Spectroscopy of CH3O (X 2E)
at
the Dissociation Limit", J. Chem. Phys. 93,
1472 (1990).
- K. Héberger, F. Temps, S. Völker, M.
Wolf, H. Gg.
Wagner: "A Direct Study of the Reaction of CH2
(X 3B1)
Radicals with Toluene in the Temperature Range 296 K < T
< 623
K", 23rd Symposium (International) on Combustion, pp 29-35, The
Combustion Institute, Pittsburgh, 1990.
- M. Koch, F. Temps, R. Wagener, H. Gg. Wagner: "On the
Reactions
of CH2 (a 1A1)
with CH3C2H,
HCN, CO2, N2O, and COS", Ber.
Bunsenges.
Phys.
Chem. 94, 645 (1990).
- C. Oehlers, F. Temps, H. Gg. Wagner, M. Wolf:
"Geschwindigkeitskonstanten der Reaktionen von CH2
(X 3B1)
mit H2CO und 1,3-C4H6",
Max-Planck-Institut für Strömungsforschung, Report 17
(1989),
ISSN 0436-1199.
- U. Bley, M. Koch, F. Temps, H. Gg. Wagner:
"Collision-Induced
Intersystem Crossing in CH2 (a1A1):
A
Quantitative Analysis
using the Mixed-State Model", Ber. Bunsenges. Phys. Chem.93,
833-841 (1989).
- F. Temps, S. Halle, P. H. Vaccaro, R. W. Field, J. L.
Kinsey:
"Collisional Deactivation of H2CO (X 1A2)
by He, Ar, Xe, and N2", J. Chem. Phys.
91,
1008-1011 (1989).
- A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht:
"State-Selective
Vibrational Excitation of OH (X 2II) Radicals
by Stimulated
Emission Pumping", Chem. Phys. Lett. 155,
614-619
(1989).
- M. Koch, F. Temps, R. Wagener, H. Gg. Wagner: "On the
Insertion
Reactions of CH2 (a 1A1)
into some
Element-Hydrogen Bonds", Z. Naturforsch. 44a,
195-204
(1989).
- J. Kappert, F. Temps: "Rotationally Resolved Laser-Induced
Fluorescene Excitation Studies of CH3O", Chem.
Phys. 132, 197-208 (1989).
- V. Seidler, F. Temps, H. Gg. Wagner, M. Wolf: "Kinetics of
the
Reactions CH2 (X 3B1)
Radicals with
NO and NO2", J. Phys. Chem. 93,
1070-1073
(1989), invited paper; F. Kaufman memorial issue.
- U. Bley, P. B. Davies, I. H. Davis, M. Koch, F. Temps:
"Measurement of the 2D5/2
- 2D3/2
Fine Structure Interval in Metastable Nitrogen Atoms at 1.15 mm by
Laser Magnetic Reconance", J. Chem. Phys. 90,
628-632
(1989).
- U. Bley, P. Dransfeld, B. Himme, M. Koch, F. Temps, H. Gg.
Wagner: "Primary Products of the Reaction between O (3P)
Atoms and C2H4 Studied
with ESR and
LMR-detection", 22nd Symposium (International) on Combustion, 997-1006
Pittsburgh, 1988.
- T. Böhland, K. Héberger, F. Temps, H.
Gg. Wagner:
"The Reaction CH2 (X 3B1)
+ C6H6", Ber.
Bunsenges. Phys. Chem. 93, 80-87 (1989).
- F. Temps: "Reply to Comment on: Vibrationally Excited
Formaldehyde: The Relationship between Vibrational Structure and
Collisional Properties", J. Chem. Soc. Faraday Trans.
II, 84,
1620-1622 (1988).
- F. Temps, S. Halle, P. H. Vaccaro, R. W. Field, J. L.
Kinsey:
"Vibrationally Excited Formaldehyde: The Relationship between
Vibrational Structure and Collisional Properties", J. Chem.
Soc.
Faraday Trans. II, 84, 1457-1482 (1988).
- P. H. Vaccaro, F. Temps, S. Halle, J. L. Kinsey, R. W.
Field:
"Polarization-Detected Transient Gain Studies of Relaxation Processes
in v4 = 1 X 1A2
Formaldehyde-h2", J. Chem. Phys.
88, 4819-4833 (1988).
- F. Temps, S. Halle, P. H. Vaccaro, R. W. Field, J. L.
Kinsey:
"Collisional Energy Transfer in Highly Vibrationally Excited H2CO
(X 1A1)", J.
Chem. Phys. 87,
1895-1897 (1987).
- T. Böhland, F. Temps, H. Gg. Wagner: "A Direct
Study of the
Reactions of CH2 (X 3B1)
Radicals
with
H and D Atoms", J. Phys. Chem. 91,
1205-1209 (1987).
- T. Böhland, F. Temps, H. Gg. Wagner: "Kinetics of
the
Reactions of CH2 (X 3B1)
Radicals
with C2H2 and C4H2
in the
Temperature Range 296 K < T < 700 K", 21st Symposium
(International) on Combustion, 841, Pittsburgh, 1986.
- T. Böhland, F. Temps, H. Gg. Wagner: "A Direct
Study of the
Reaction CH2 (X 3B1)
+ C2H4
in the Temperature Range 296 K < T < 728 K", Ber.
Bunsenges.
Phys. Chem. 90, 468-475 (1986).
- T. Böhland, S. Dóbé, F.
Temps, H. Gg. Wagner:
"Kinetics of the Reactions between CH2 Radicals
and
Hydrocarbons
in the Temperature Range 296 K < T < 728 K", Proceedings
of the
17th
International Symposium on Free Radicals, Snow Mountain, Colorado, NBS
Special
Publication 716, 38 (1986).
Publications
1981
- 1985:
- T. Böhland, S. Dóbé, F.
Temps, H. Gg. Wagner:
"Kinetics of the Reaction between CH2 (X 3B1)-Radicals
and Saturated Hydrocarbons in the Temperature Range 296 < T
< 705
K",
Max-Planck-Institut für Strömungsforschung, Report 11
(1985),
ISSN
0436-1199.
- T. Böhland, F. Temps, H. Gg. Wagner: "The
Contributions of
Intersystem Crossing and Reaction in the Removal of CH2
(a 1A1)
by Hydrocarbons Studied with the LMR", Max-Planck-Institut für
Strömungsforschung, Report 10 (1985), ISSN 0436-1199.
- S. Dóbé, F. Temps, H. Gg. Wagner:
"The Reaction of
CH2OH Radicals with O2 Studied
by Laser Magnetic
Resonance
Technique", Z. Naturforsch. 40a,
1289-1298 (1985).
- T. Böhland, S. Dóbé, F.
Temps, H. Gg. Wagner:
"Kinetics of the Reactions between CH2 (X 3B1)-Radicals
and Saturated Hydrocarbons in the Temperature Range 296 < T
< 707
K", Ber. Bunsenges. Phys. Chem. 89,
1110-1116 (1985).
- T. Böhland, F. Temps, H. Gg. Wagner: "The
Contributions of
Intersystem Crossing and Reaction in the Removal of CH2
(a 1A1)
by Hydrocarbons Studied with the LMR", Ber. Bunsenges. Phys.
Chem.89,
1013-1018 (1985).
- P. B. Davies, A. H. Ferguson, D. P. Stern, F. Temps: "Far
Infrared LMR Spectroscopy of NF (a 1Delta, v=0,
1, 2)", J.
Mol. Spectrosc.113, 28-38 (1985).
- S. Dóbé, T. Böhland, F.
Temps, H. Gg. Wagner:
"A Direct Study of the Reactions of CH2 (X 3B1)-Radicals
with Selected Hydrocarbons in the Temperature Range 296 K < T
<
705 K", Ber. Bunsenges. Phys. Chem. 89,
432-441 (1985).
- P. B. Davies, P. Dransfeld, F. Temps, H. Gg. Wagner:
"Detection
of NH2O Radicals by Far-Infrared Laser Magnetic
Resonance
Spectroscopy", Max-Planck-Institut für
Strömungsforschung,
Report 6 (1984), ISSN 0436-1199.
- T. Böhland, F. Temps, H. Gg. Wagner: "An
LMR-Spectrometer
Operating up to mm-Wavelengths for Kinetic Investigations with
Discharge Flow and Flas
Photolysis Systems", Z. Phys. Chem., NF 142,
129-140
(1984).
- T. Böhland, F. Temps, H. Gg. Wagner: "Direct
Investigation
of the Reaction CH2 (X 3B1)
+ O (3P)
with the LMR", Ber. Bunsenges. Phys. Chem. 88,
1222-1228 (1984).
- P. B. Davies, P. Dransfeld, F. Temps, H. Gg. Wagner:
"Detection
of the NH2O Radical by Far Infrared LMR", J.
Chem. Phys. 81, 3763-3765 (1984).
- P. Dransfeld, W. Hack, H. Kurzke, F. Temps, H. Gg. Wagner:
"Direct Studies of Elementary Reactions of NH2
Radicals in
the Gas Phase", 20th International Symposium on Combustion, p. 655-663,
The Combustion Institute, Pittsburgh, 1984.
- T. Böhland, F. Temps: "Direct Determination of the
Rate
Constant for the Reaction CH2 + H = CH + H2",
Ber.
Bunsenges. Phys. Chem. 88, 459-461 (1984).
- T. Böhland, F. Temps, H. Gg. Wagner: "Direct
Determination
of the Rate Constant for the Reaction CH2 + O2
with a
LMR-Spectrometer", Ber. Bunsenges. Phys. Chem. 88,
455-458
(1984).
- F. Temps, H. Gg. Wagner: "Rate Constants for the Reaction
of OH
Radicals with CH2O and HCO", Ber.
Bunsenges. Phys. Chem. 88, 415-418 (1984).
- F. Temps, H. Gg. Wagner: "Kinetics of the Reactions of HCO
with
HCO and O2", Ber. Bunsenges. Phys.
Chem. 88,
410-414 (1984).
- F. Temps: "Untersuchung von Radikal-Radikal-Reaktionen mit
Hilfe
eines FIR-LMR-Spektrometers", Dissertation, Max-Planck-Institut
für
Strömungsforschung, Bericht 4 (1983), ISSN 0436-1199.
- F. Temps, H. Gg. Wagner, P. B. Davies, D. P. Stern, K. O.
Christe: "Far Infrared Laser Magnetic Resonance Detection of FO2",
J. Phys. Chem. 87, 5068-5070
(1983).
- P. B. Davies, F. Temps, H. Gg. Wagner, D. P. Stern: "The FO2
Radical and LMR Spectra in Reactions of Fluorine Atoms",
Max-Planck-Institut für Strömungforschung, Bericht 19
(1982),
ISSN 0436-1199.
- F. Temps, H. Gg. Wagner: "Untersuchungen zur Produktbildung
in
der Reaktion von Sauerstoffatomen mit Ethylen," Max-Planck-Institut
für
Strömungsforschung, Report 18 (1982), ISSN 0436-1199.
- F. Temps, H. Gg. Wagner: "Untersuchungen zur Reaktion OH +
HO2
= H2O + O2 mit Hilfe
eines Laser-Magnetischen
Resonanz-Spektrometers", Ber. Bunsenges. Phys. Chem.86,
119-125 (1982).
- F. Temps, H. Gg. Wagner: "Strong Far-Infrared Laser Action
in
Carbonyl Fluoride and Vinyl Fluoride", Appl. Phys. B
29,
13-14 (1982).
- P. B. Davies, W. Hack, F. Temps: "Recent Developments in
Laser
Magnetic Resonance Spectroscopy", Max-Planck-Institut für
Strömungsforschung, Report 15 (1981), ISSN 0436-1199.
- P. B. Davies, F. Temps: "Far Infrared Laser Magnetic
Resonance
Spectrum of NF (a 1Delta)", J. Chem.
Phys. 74,
6556-6559 (1981).
Publications
1979
- 1980:
- F. Temps, H. Gg. Wagner: "Untersuchung der Reaktion OH + HO2
H2O + O2 mit Hilfe der
Lasermagnetischen
Resonanz", Max-Planck-Institut für
Strömungsforschung, Report
18A (1980).
- A. W. Preuss, F. Temps, H. Gg. Wagner: "Aufbau und
Eigenschaften
eines optisch gepumpten FIR-LMR-Spektrometers", Max-Planck-Institut
für
Strömungsforschung, Report 18 (1980), ISSN 0436-1199.
- W. Hack, A. W. Preuss, F. Temps, H. Gg. Wagner, K.
Hoyermann:
"Direct Determination of the Rate Constant of the Reaction NO + NO2
NO2 + OH with the LMR", Int. J. Chem.
Kinet. XII,
851-860 (1980).
- F. Temps: "Untersuchung von Reaktionen des
Hydroperoxylradikals
mit Hilfe eines kombinierten ESR-LMR-Spektrometers",
Max-Planck-Institut für Strömungsforschung, Report 16
(1979),
ISSN 0436-1199.
- W. Hack, A. W. Preuss, F. Temps, H. Gg. Wagner:
"The
Reaction O + HO2 OH + O2
Studied with a
LMR-ESR-Spectrometer", Ber. Bunsenges. Phys. Chem. 83,
1275-1279 (1979).
- P. B. Davies, W. Hack, A. W. Preuss, F. Temps: "Far
Infrared
Laser Magnetic Resonance Spectra of Vibrationally Excited OH", Chem.
Phys.
Lett. 64, 94-97 (1979).
Other
publications by group members:
- G. Friedrichs, M. Colberg, J. Dammeier, T. Bentz, M.
Olzmann,
"HCO Formation in the Thermal Unimolecular Decomposition of Glyoxal:
Rotational and Weak Collision Effects", Phys. Chem.
Chem. Phys. 10,
6520 - 6533 (2008). DOI: 10.1039/b809992h
- G. Friedrichs: "Sensitive Absorption Methods for
Quantitative Gas
Phase Kinetic Measurements. Part 1: Frequency Modulation Spectroscopy",
Z. Physik. Chem. 222,
1 (2008).
- G. Friedrichs: "Sensitive Absorption Methods for
Quantitative Gas
Phase
Kinetic Measurements. Part 2: Cavity Ringdown Spectroscopy", Z.
Physik. Chem. 222,
31 (2008).
- J. Dammeier, M. Colberg, G. Friedrichs: "Wide Temperature
Range
(T = 295 K
and 770 - 1305 K) Study of the Kinetics of the Reactions HCO + NO and
HCO + NO2 using Frequency Modulation
Spectroscopy", Phys.
Chem. Chem. Phys. 9,
4177-4188 (2007).
- G. Friedrichs: "Jahresrückblick
Physikalische
Chemie: Reaktionskinetik", Nachr.
Chem. 54,
285-287
(2006).
- M. Colberg, G. Friedrichs: "Room Temperature and Shock Tube
Study
of the Reaction HCO + O2 using the Photolysis of
Glyoxal as
an
Efficient
HCO Source", J. Phys.
Chem. A 106,
160-170 (2006).
- E. Breitbarth, M. M. Mills, G. Friedrichs, J. LaRoche:
"Importance
of
Gas Solubility Coefficients as a Function of Temperature and Salinity
for Use in Nitrogen Fixation Assays", Limnol.
and Oceanog.: Methods 2,
282-288 (2004).
- G. Friedrichs, D. F. Davidson, R. K. Hanson: "Validation of
a
Thermal
Decomposition Mechanism of Formaldehyde by Detection of CH2O
and HCO
behind Shock Waves", Int.
J. Chem.
Kinet. 36,
157-169
(2004).
- S. Song, D. M. Golden, R. K. Hanson, C. T. Bowman, J. P.
Senosiain,
C. B. Musgrave, G. Friedrichs: "A Shock Tube Study of the Reaction NH2
+
CH4 => NH3 + CH3",
Int. J. Chem. Kinet.
35,
304-309 (2003).
- F. Nettesheim, J. Zipfel,
U. Olsson, F.
Renth, P. Lindner, W. Richtering: "Pathway of the shear-induced transition
between planar lamellae and multilamellar vesicles as studied by
time-resolved
scattering techniques", Langmuir 19,
3603-3618 (2003).
- F. Winther, St. Meyer, F. M. Nicolaisen: "The Infrared
Spectrum
of Methylketene", J. Molec. Struct. 611, 9-22 (2002).
- H. Dreizler, N. Hansen: "High Resolution Microwave
Spectroscopy
of Ethyl Vinyl Ether: Accurate Determination of the Methyl Top Internal
Rotation Barrier", Z. Naturforsch. 55a,
481 (2000).
- N. Hansen, H. Mäder, T. Bruhn: "A Molecular Beam -
Fourier
Transform Microwave Study of o-Tolunitrile: 14N
Nuclear
Quadrupole Coupling and Internal Rotation Effects", Mol. Phys.
97,
587 (1999).
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